SA YELLOW

Page 3/7 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 04.08.2010 Revision: 04.08.2010 Trade name:B1466 LATEX COLOR HA/SA YELL...

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Page 1/7

Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 04.08.2010

Revision: 04.08.2010

1 Identification of the substance/preparation and of the company/undertaking · Product details · Trade name: B1466 LATEX COLOR HA/SA YELLOW · Application of the substance / the preparation Boysen Latex Colors are concentrated acrylic based tinting paints for Boysen Permacoat Latex Paints, Boysen Healthy Home and Boysen Wallguard Dirt Resisting Latex. They disperse easily and produce tints from pastel to medium shades with even finishes. · Manufacturer/Supplier: Pacific Paint (Boysen) Philippines, Inc. 292 D. Tuazon St., Quezon City 1115 Philippines · Further information obtainable from: Product safety department · Information in case of emergency: Telephone 4os. : +63 2 364 3505; +63 2 365 0561 Facsimile 4os. : +63 2 367 8878; +63 2 364 0472 Email Address : [email protected] Website Address : www.boysen.com.ph

2 Hazards identification · Hazard description: Xi Irritant · Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. R 43 May cause sensitisation by skin contact. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. · GHS label elements Warning 3.4/1 - May cause an allergic skin reaction. · Prevention: Avoid breathing dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. · Response: IF O4 SKI4: Wash with plenty of soap and water. Specific treatment (see on this label). If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. · Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations.

3 Composition/information on ingredients · Chemical characterization · Description: Mixture of substances listed below with nonhazardous additions. (Contd. on page 2) RP

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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 04.08.2010

Trade name: B1466

Revision: 04.08.2010

LATEX COLOR HA/SA YELLOW (Contd. of page 1)

· Dangerous components: CAS: 471-34-1 calcium carbonate EI4ECS: 207-439-9 CAS: 2512-29-0 Butanamide CAS: 111-46-6 2,2'-oxybisethanol Xn; R 22 EI4ECS: 203-872-2 Danger: 3.1.O/3 CAS: 1336-21-6 ammonia EI4ECS: 215-647-6 C, 4; R 34-50 Danger: 3.2/1B Warning: 2.5/D; 4.1.A/1 CAS: 55965-84-9 mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2Hisothiazol-3-one [EC no. 220-239-6] (3:1) mixture of: 5chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-4isothiazolin-3-one [EC no. 220-239-6] (3:1) T, C, 4; R 23/24/25-34-43-50/53 Danger: 3.1.O/2, 3.1.D/2, 3.1.I/2, 3.4.S/1; 3.2/1B Warning: 4.1.C/1 · Additional information: For the wording of the listed risk phrases refer to section 16. CAS: 7732-18-5 water, distilled, conductivity or of similar purity EI4ECS: 231-791-2

25-50% 2.5-10% ≤ 2.5%

≤ 2.5%

≤ 2.5%

25-50%

4 First aid measures · After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: If symptoms persist consult doctor.

5 Fire-fighting measures · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Protective equipment: 4o special measures required.

6 Accidental release measures · Person-related safety precautions: 4ot required. · Measures for environmental protection: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. · Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. RP

(Contd. on page 3)

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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 04.08.2010

Trade name: B1466

Revision: 04.08.2010

LATEX COLOR HA/SA YELLOW (Contd. of page 2)

7 Handling and storage · Handling: · Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. · Information about fire - and explosion protection: 4o special measures required. · Storage: · Requirements to be met by storerooms and receptacles: 4o special requirements. · Information about storage in one common storage facility: 4ot required. · Further information about storage conditions: 4one.

8 Exposure controls/personal protection · Additional information about design of technical facilities: 4o further data; see item 7. · Ingredients with limit values that require monitoring at the workplace: 471-34-1 calcium carbonate PEL (USA) 15* 5** mg/m³ *total dust **respirable fraction REL (USA) 10* 5** mg/m³ *total dust **respirable fraction TLV (USA) TLV withdrawn 2512-29-0 Butanamide TLV (USA) Short-term value: 10 mg/m³ 111-46-6 2,2'-oxybisethanol WEEL (USA) 10 mg/m³ · Additional information: The lists valid during the making were used as basis. · Personal protective equipment: · General protective and hygienic measures: Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. · Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 4) RP

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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 04.08.2010

Trade name: B1466

Revision: 04.08.2010

LATEX COLOR HA/SA YELLOW (Contd. of page 3)

· Eye protection: Goggles recommended during refilling

9 Physical and chemical properties · General Information Form: Colour: Odour:

Fluid According to product specification Characteristic

· Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 100°C · Flash point:

4ot applicable.

· Ignition temperature:

200°C

· Self-igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Vapour pressure at 20°C:

23 hPa

· Density:

1.23-1.36 Kg/Li

· Solubility in / Miscibility with Fully miscible. water: · pH-value:

8.5-9.0

· Viscosity:

90-95 KU

· Solvent content: Organic solvents: Water: VOC (EC)

1.6 % 33.5 % 1.57 %

· Solids content:

64.3 %

10 Stability and reactivity · Thermal decomposition / conditions to be avoided: 4o decomposition if used according to specifications. · Dangerous reactions 4o dangerous reactions known. · Dangerous decomposition products: 4o dangerous decomposition products known.

11 Toxicological information · Acute toxicity: · Primary irritant effect: · on the skin: Cause mild irritation · on the eye: 4o irritating effect. · Sensitization: Sensitization possible through skin contact. · Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant · Sensitisation May cause sensitisation by skin contact. RP

(Contd. on page 5)

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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 04.08.2010

Trade name: B1466

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LATEX COLOR HA/SA YELLOW (Contd. of page 4)

12 Ecological information · General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.

13 Disposal considerations · Product: · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. · Recommended cleansing agents: Water, if necessary together with cleansing agents.

14 Transport information · Land transport ADR/RID (cross-border) · ADR/RID class: · Maritime transport IMDG: · IMDG Class: · Marine pollutant: 4o · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: · U/ "Model Regulation": -

15 Regulatory information · Philippines Inventory of Chemicals and Chemical Substances 471-34-1 calcium carbonate 2512-29-0 Butanamide 111-46-6 2,2'-oxybisethanol 25265-77-4 2,2,4-trimethyl-1,3 pentanediol-monoisobutyrate Texanol 9004-58-4 Ethylhydroxyethyl cellulose Cellulose Ether ethyl-2-hydroxyethylether ethyl-2-hydroxyethyl cellulose celluloseethylhydroxyethyl Ethylhydroxyethyl cellulose Cellulose ethyl hydroxyethyl ether Etulose 1336-21-6 ammonia 9036-19-5 Polyethylene glycol octylphenyl ether 50-00-0 formaldehyde 25322-68-3 Polyethylene glycol (Contd. on page 6) RP

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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 04.08.2010

Trade name: B1466

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LATEX COLOR HA/SA YELLOW (Contd. of page 5)

10377-60-3 Magnesium nitrate 6-hydrate Magnesium (II), hexahydrate 4itric acid, magnesium salt, hexahydrate 55965-84-9 mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl2Hisothiazol-3-one [EC no. 220-239-6] (3:1) mixture of: 5-chloro-2-methyl-4-isothiazolin-3one [EC no. 247-500-7] and 2-methyl-4-isothiazolin-3-one [EC no. 220-239-6] (3:1) · Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. · Code letter and hazard designation of product: Xi Irritant

· Hazard-determining components of labelling: mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2Hisothiazol-3-one [EC no. 220-239-6] (3:1) mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2methyl-4-isothiazolin-3-one [EC no. 220-239-6] (3:1) · Risk phrases: 43 May cause sensitisation by skin contact. · Safety phrases: 2 Keep out of the reach of children. 23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). 24 Avoid contact with skin. 29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. 37 Wear suitable gloves. 46 If swallowed, seek medical advice immediately and show this container or label.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant R-phrases 22 Harmful if swallowed. 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. 34 Causes burns. 43 May cause sensitisation by skin contact. 50 Very toxic to aquatic organisms. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Department issuing MSDS: Safety, Health and Environment Department Gretchen A. Fontejon - [email protected] Joanne C. Ysrael - [email protected] · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals (Contd. on page 7) RP

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Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 04.08.2010

Trade name: B1466

Revision: 04.08.2010

LATEX COLOR HA/SA YELLOW (Contd. of page 6)

VOC: Volatile Organic Compounds (USA, EU)

· * Data compared to the previous version altered. 04.08.2010 RP

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